1. Mr. and Mrs. Smith - Brad Pitt and Angelina Jolie
2. Far and Away - Tom Cruise and Nicole Kidman
3. The Break-Up - Jennifer Aniston and Vince Vaughn (self-fulfilling prophecy btw)
4. Jab We Met - Shahid Kapoor and Kareena Kapoor (not married or related despite the same last name)
5. The Marrying Man - Alec Baldwin and Kim Basinger
6. Hackers - Johnny Lee Miller and Angelina Jolie
7. Pushing Tin - Angelina Jolie and Billy Bob Thornton
8. Scooby Doo 1 & 2 - Freddie Prince jr. and Sarah Michelle Gellar
9. The Long, Long Trailer - Desi Arnaz and Lucille Ball
10. Cruel Intentions - Reese Witherspoon and Ryan Phillippe
11. U, Me aur Hum - Ajay Devgan and Kajol
12. Innerspace - Meg Ryan and Dennis Quaid
13. LolliLove - James Dunn and Jenna Fischer
14. Bugsy - Annette Bening and Warren Beatty
15. Overboard - Kurt Russell and Goldie Hawn
16. Kyun! Ho Gaya Na.../Kuch Naa Kaho - Abhishek Bachchan and Aishwarya Rai
17. No Man of Her Own--Clark Gable and Carole Lombard
18. Eyes Wide Shut (once again Kidman - Cruise)
19. To Have And Have Not - Humphrey Bogart and Lauren Bacall
20. Adam's Rib - Katherine Hepburn and Spencer Tracy
21. Flesh and Bone - Meg Ryan and Dennis Quaid
22. My Pal Trigger - Roy Rogers and Dale Evans
23. Cleopatra - Richard Burton & Elizabeth Taylor
24. The Postman Always Rings Twice - Jack Nicholson and Anjelica Huston